However, if you mean the first time Luffy uses basic to knock out weak-willed people, that is Episode 413 (at the Sabaody Archipelago, after the Straw Hats are separated by Kuma).
The term "Supreme Haki" isn't commonly used; fans and the community sometimes refer to Conqueror's Haki by this term due to a mistranslation in early fan translations and English dubbed versions, which referred to it as "Supreme Haki" due to early inaccurate renderings.
Because Luffy’s mastery of this rare power evolved over hundreds of episodes, there isn't just one answer. Depending on whether you are looking for the first accidental flicker or his ultimate mastery, here are the key episodes where Luffy uses Supreme Haki. 1. The Very First Hint: Episode 389
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However, if you mean the first time Luffy uses basic to knock out weak-willed people, that is Episode 413 (at the Sabaody Archipelago, after the Straw Hats are separated by Kuma).
The term "Supreme Haki" isn't commonly used; fans and the community sometimes refer to Conqueror's Haki by this term due to a mistranslation in early fan translations and English dubbed versions, which referred to it as "Supreme Haki" due to early inaccurate renderings.
Because Luffy’s mastery of this rare power evolved over hundreds of episodes, there isn't just one answer. Depending on whether you are looking for the first accidental flicker or his ultimate mastery, here are the key episodes where Luffy uses Supreme Haki. 1. The Very First Hint: Episode 389